python idle使用kivy框架开发手机应用，在手机界面按下“开始录音”的按钮时调用百度api开始录音并识别，同时在文本框中展现识别结果，按下”清空”按钮清除文本框内容；当识别出“加载样品溶液”或者按下界面上的”加载样品溶液“按钮时调用手机蓝牙向hc-05型号的蓝牙发送字母a，识别出“加载清洗液一“的时候通过蓝牙发送字母b；识别出“加载清洗液二”或按下按钮的时候发送字母c，识别出“加载洗脱溶液”时发送字母d，按下“总操作”的按钮时发送字母e完整代码生成

这里提供一个基本的框架，需要根据具体的需求进行修改和完善。

import kivy
from kivy.app import App
from kivy.uix.boxlayout import BoxLayout
from kivy.uix.button import Button
from kivy.uix.textinput import TextInput
import speech_recognition as sr
import requests
import bluetooth

# 百度API的相关参数
APP_ID = 'your_app_id'
API_KEY = 'your_api_key'
SECRET_KEY = 'your_secret_key'

# HC-05蓝牙模块相关参数
HC05_ADDR = 'your_hc05_bluetooth_address'
HC05_PORT = 1

# 定义一个布局类
class MyBoxLayout(BoxLayout):
    
    def __init__(self, **kwargs):
        super().__init__(**kwargs)
        
        # 创建文本框和按钮
        self.text_input = TextInput()
        self.start_button = Button(text='开始录音', on_press=self.start_recording)
        self.clear_button = Button(text='清空', on_press=self.clear_text)
        self.load_sample_button = Button(text='加载样品溶液', on_press=self.load_sample)
        self.load_cleaner1_button = Button(text='加载清洗液一', on_press=self.load_cleaner1)
        self.load_cleaner2_button = Button(text='加载清洗液二', on_press=self.load_cleaner2)
        self.load_elution_button = Button(text='加载洗脱溶液', on_press=self.load_elution)
        self.total_operation_button = Button(text='总操作', on_press=self.total_operation)
        
        # 将文本框和按钮添加到布局中
        self.add_widget(self.text_input)
        self.add_widget(self.start_button)
        self.add_widget(self.clear_button)
        self.add_widget(self.load_sample_button)
        self.add_widget(self.load_cleaner1_button)
        self.add_widget(self.load_cleaner2_button)
        self.add_widget(self.load_elution_button)
        self.add_widget(self.total_operation_button)
        
        # 初始化语音识别器
        self.recognizer = sr.Recognizer()
        
    # 开始录音并识别
    def start_recording(self, *args):
        with sr.Microphone() as source:
            print('开始录音...')
            audio = self.recognizer.listen(source)
            try:
                print('识别中...')
                text = self.recognizer.recognize_baidu(audio, APP_ID, API_KEY, SECRET_KEY) # 调用百度API识别语音
                print(text)
                self.text_input.text = text # 将识别结果显示在文本框中
            except:
                print('识别失败')
    
    # 清空文本框
    def clear_text(self, *args):
        self.text_input.text = ''
    
    # 加载样品溶液
    def load_sample(self, *args):
        self.send_command('a')
    
    # 加载清洗液一
    def load_cleaner1(self, *args):
        self.send_command('b')
    
    # 加载清洗液二
    def load_cleaner2(self, *args):
        self.send_command('c')
    
    # 加载洗脱溶液
    def load_elution(self, *args):
        self.send_command('d')
    
    # 总操作
    def total_operation(self, *args):
        self.send_command('e')
    
    # 发送指令到HC-05蓝牙模块
    def send_command(self, command):
        try:
            sock = bluetooth.BluetoothSocket(bluetooth.RFCOMM)
            sock.connect((HC05_ADDR, HC05_PORT))
            sock.send(command)
            sock.close()
            print('指令已发送:', command)
        except:
            print('发送指令失败')
            
# 定义一个应用程序类
class MyApp(App):
    
    def build(self):
        return MyBoxLayout()
    
if __name__ == '__main__':
    MyApp().run()

需要注意的是：

1. 代码中用到了百度API和HC-05蓝牙模块，需要先申请相应的账号和硬件设备，并在代码中填写相应的参数。
2. 代码中使用了第三方库speech_recognition和bluetooth，需要先使用pip安装。