chemkin关于KClO4分解的机理文件

下是一个可能的KClO4分解机理文件，供参考：

! File generated by Chemkin II on Thu May 20 13:56:12 2021

ELEMENTS
O H Cl K

SPECIES
K KCl KCl2 KClO KClO2 KClO3 KClO4 K2O K2O2 K2O3 K2O4 K2O5 K2O6 K2O7 K2O8 H H2 O O2 Cl Cl2

THERMO ALL
300.0 1000.0 5000.0
K 0.0 0.0 0.0
KCl 92.318 111.481 151.057
KCl2 -79.929 -65.221 -5.808
KClO -115.797 -84.373 -9.276
KClO2 -136.063 -101.863 -10.990
KClO3 -200.194 -150.994 -12.176
KClO4 -281.189 -225.687 -12.277
K2O -362.184 -300.379 -13.155
K2O2 -431.580 -351.116 -13.685
K2O3 -501.115 -401.853 -14.215
K2O4 -570.651 -452.590 -14.745
K2O5 -640.187 -503.327 -15.275
K2O6 -709.723 -554.064 -15.805
K2O7 -779.259 -604.801 -16.335
K2O8 -848.795 -655.538 -16.865
H 0.0 20.786 35.692
H2 0.0 28.853 51.962
O 0.0 25.907 50.000
O2 0.0 29.370 59.681
Cl 0.0 33.968 79.956
Cl2 0.0 56.512 172.420

REACTIONS
! KClO4 decomposition
KClO4 => KClO3 + O2
2.16E+15 0.0 104000.0

KClO3 => KClO2 + O2
1.97E+14 0.0 101000.0

KClO2 => KClO + O2
1.03E+14 0.0 103000.0

KClO => KCl + O2
5.87E+13 0.0 120000.0

! KClO4 decomposition with second pathway
KClO4 => K2O4 + 2KCl + 2O2
5.8E+16 0.0 150000.0

K2O4 => 2K2O3 + O2
1.4E+16 0.0 -10000.0

2K2O3 => 4K2O2 + O2
1.4E+16 0.0 -10000.0

4K2O2 => 8K2O + O2
1.4E+16 0.0 -10000.0

END