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ANSYS_Fluent_15.0_燃料电池模块手册(en) 针对使用Fluent进行燃料电池仿真,载入专用的model,以更便捷的进行燃料电池仿真
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ANSYS Fluent Fuel Cell Modules Manual
Release 15.0ANSYS, Inc.
November 2013Southpointe
275 Technology Drive
Canonsburg, PA 15317
ANSYS, Inc. is
certified to ISO
9001:2008.
ansysinfo@ansys.com
http://www.ansys.com
(T) 724-746-3304
(F) 724-514-9494

Copyright and Trademark Information
© 2013 SAS IP, Inc. All rights reserved. Unauthorized use, distribution or duplication is prohibited.
ANSYS, ANSYS Workbench, Ansoft, AUTODYN, EKM, Engineering Knowledge Manager, CFX, FLUENT, HFSS and any
and all ANSYS, Inc. brand, product, service and feature names, logos and slogans are registered trademarks or
trademarks of ANSYS, Inc. or its subsidiaries in the United States or other countries. ICEM CFD is a trademark used
by ANSYS, Inc. under license. CFX is a trademark of Sony Corporation in Japan. All other brand, product, service
and feature names or trademarks are the property of their respective owners.
Disclaimer Notice
THIS ANSYS SOFTWARE PRODUCT AND PROGRAM DOCUMENTATION INCLUDE TRADE SECRETS AND ARE CONFID-
ENTIAL AND PROPRIETARY PRODUCTS OF ANSYS, INC., ITS SUBSIDIARIES, OR LICENSORS. The software products
and documentation are furnished by ANSYS, Inc., its subsidiaries, or affiliates under a software license agreement
that contains provisions concerning non-disclosure, copying, length and nature of use, compliance with exporting
laws, warranties, disclaimers, limitations of liability, and remedies, and other provisions. The software products
and documentation may be used, disclosed, transferred, or copied only in accordance with the terms and conditions
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ANSYS, Inc. is certified to ISO 9001:2008.
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For U.S. Government users, except as specifically granted by the ANSYS, Inc. software license agreement, the use,
duplication, or disclosure by the United States Government is subject to restrictions stated in the ANSYS, Inc.
software license agreement and FAR 12.212 (for non-DOD licenses).
Third-Party Software
See the
legal information in the product help files for the complete Legal Notice for ANSYS proprietary software
and third-party software. If you are unable to access the Legal Notice, please contact ANSYS, Inc.
Published in the U.S.A.

Table of Contents
Using This Manual ........................................................................................................................................ v
1. The Contents of This Manual ................................................................................................................ v
2.The Contents of the Fluent Manuals ..................................................................................................... v
3.Typographical Conventions ................................................................................................................ vii
4. Mathematical Conventions ................................................................................................................ vii
5. Technical Support ............................................................................................................................. viii
1. Fuel Cell and Electrolysis Model Theory ................................................................................................. 1
1.1. Introduction ..................................................................................................................................... 1
1.1.1. Introduction to PEMFC ............................................................................................................. 2
1.1.2. Introduction to SOFC ............................................................................................................... 3
1.1.3. Introduction to Electrolysis ....................................................................................................... 3
1.2. Electrochemistry Modeling ............................................................................................................... 3
1.3. Current and Mass Conservation ......................................................................................................... 6
1.4. Heat Source ...................................................................................................................................... 7
1.5. Liquid Water Formation,Transport, and its Effects (PEMFC Only) ......................................................... 7
1.6. Properties ......................................................................................................................................... 8
1.7. Transient Simulations ...................................................................................................................... 10
1.8. Leakage Current (Cross-Over Current) ............................................................................................. 10
2. Using the Fuel Cell and Electrolysis Model ........................................................................................... 13
2.1. Introduction ................................................................................................................................... 13
2.2. Geometry Definition for the Fuel Cell and Electrolysis Model ............................................................ 13
2.3. Installing the Fuel Cell and Electrolysis Model .................................................................................. 14
2.4. Loading the Fuel Cell and Electrolysis Module .................................................................................. 14
2.5. Setting Up the Fuel Cell and Electrolysis Module .............................................................................. 14
2.6. Modeling Fuel Cells and Electrolysis ................................................................................................ 15
2.6.1. Specifying Model Options ...................................................................................................... 17
2.6.2. Specifying Model Parameters ................................................................................................. 19
2.6.3. Specifying Anode Properties .................................................................................................. 20
2.6.3.1. Specifying Current Collector Properties for the Anode .................................................... 21
2.6.3.2. Specifying Flow Channel Properties for the Anode ......................................................... 22
2.6.3.3. Specifying Porous Electrode Properties for the Anode .................................................... 23
2.6.3.4. Specifying Catalyst Layer Properties for the Anode ......................................................... 24
2.6.3.5. Specifying Cell Zone Conditions for the Anode ............................................................... 25
2.6.4. Specifying Electrolyte/Membrane Properties .......................................................................... 25
2.6.4.1. Specifying Cell Zone Conditions for the Membrane ........................................................ 26
2.6.5. Specifying Cathode Properties ................................................................................................ 26
2.6.5.1. Specifying Current Collector Properties for the Cathode ................................................. 26
2.6.5.2. Specifying Flow Channel Properties for the Cathode ....................................................... 27
2.6.5.3. Specifying Porous Electrode Properties for the Cathode ................................................. 28
2.6.5.4. Specifying Catalyst Layer Properties for the Cathode ...................................................... 29
2.6.5.5. Specifying Cell Zone Conditions for the Cathode ............................................................ 30
2.6.6. Setting Advanced Properties .................................................................................................. 30
2.6.6.1. Setting Contact Resistivities for the Fuel Cell and Electrolysis Model ................................ 30
2.6.6.2. Setting Coolant Channel Properties for the Fuel Cell and Electrolysis Model .................... 31
2.6.6.3. Managing Stacks for the Fuel Cell and Electrolysis Model ................................................ 32
2.6.7. Reporting on the Solution ...................................................................................................... 34
2.7. Modeling Current Collectors ........................................................................................................... 35
2.8. Fuel Cell and Electrolysis Model Boundary Conditions ...................................................................... 36
2.9. Solution Guidelines for the Fuel Cell and Electrolysis Model ............................................................. 37
2.10. Postprocessing the Fuel Cell and Electrolysis Model ....................................................................... 38
iii
Release 15.0 - © SAS IP, Inc. All rights reserved. - Contains proprietary and confidential information
of ANSYS, Inc. and its subsidiaries and affiliates.

2.11. User-Accessible Functions ............................................................................................................. 39
2.11.1. Compiling the Customized Fuel Cell and Electrolysis Source Code ......................................... 42
2.11.1.1. Compiling the Customized Source Code Under Linux ................................................... 42
2.11.1.2. Compiling the Customized Source Code Under Windows ............................................. 43
2.12. Using the Fuel Cell and Electrolysis Text User Interface ................................................................... 44
2.12.1. IV-Curve Calculations Using the Text Interface ....................................................................... 46
3. SOFC Fuel Cell With Unresolved Electrolyte Model Theory .................................................................. 49
3.1. Introduction ................................................................................................................................... 49
3.2.The SOFC With Unresolved Electrolyte Modeling Strategy ................................................................ 50
3.3. Modeling Fluid Flow, Heat Transfer, and Mass Transfer ...................................................................... 51
3.4. Modeling Current Transport and the Potential Field ......................................................................... 51
3.4.1. Cell Potential .......................................................................................................................... 52
3.4.2. Activation Overpotential ........................................................................................................ 53
3.4.3.Treatment of the Energy Equation at the Electrolyte Interface .................................................. 54
3.4.4.Treatment of the Energy Equation in the Conducting Regions ................................................. 56
3.5. Modeling Reactions ........................................................................................................................ 56
3.5.1. Modeling Electrochemical Reactions ...................................................................................... 56
3.5.2. Modeling CO Electrochemistry ............................................................................................... 57
4. Using the Solid Oxide Fuel Cell With Unresolved Electrolyte Model .................................................... 59
4.1. Installing the Solid Oxide Fuel Cell With Unresolved Electrolyte Model ............................................. 59
4.2. Loading the Solid Oxide Fuel Cell With Unresolved Electrolyte Module ............................................. 59
4.3. Solid Oxide Fuel Cell With Unresolved Electrolyte Module Set Up Procedure ..................................... 60
4.4. Setting the Parameters for the SOFC With Unresolved Electrolyte Model .......................................... 66
4.5. Setting Up the Electrochemistry Parameters .................................................................................... 68
4.6. Setting Up the Electrode-Electrolyte Interfaces ................................................................................ 69
4.6.1. Setting Up the Anode Electrode-Electrolyte Interface .............................................................. 69
4.6.2. Setting Up the Cathode Electrode-Electrolyte Interface ........................................................... 70
4.6.3. Setting Up the Tortuosity Parameters ...................................................................................... 71
4.7. Setting Up the Electric Field Model Parameters ................................................................................ 72
4.8. User-Accessible Functions for the Solid Oxide Fuel Cell With Unresolved Electrolyte Model ............... 73
4.8.1. Compiling the Customized Solid Oxide Fuel Cell With Unresolved Electrolyte Source Code ...... 74
4.8.1.1. Compiling the Customized Source Code Under Linux ..................................................... 75
4.8.1.2. Compiling the Customized Source Code Under Windows ............................................... 75
4.9. Using the Solid Oxide Fuel Cell With Unresolved Electrolyte Text User Interface ................................ 76
Bibliography ............................................................................................................................................... 79
Index .......................................................................................................................................................... 81
Release 15.0 - © SAS IP, Inc. All rights reserved. - Contains proprietary and confidential information
of ANSYS, Inc. and its subsidiaries and affiliates.iv
Fuel Cell Modules Manual

Using This Manual
This preface is divided into the following sections:
1.The Contents of This Manual
2.The Contents of the Fluent Manuals
3.Typographical Conventions
4. Mathematical Conventions
5.Technical Support
1.The Contents of This Manual
The ANSYS Fluent Fuel Cell Modules Manual provides information about the background and the usage
of two separate add-on fuel cell modules for ANSYS Fluent. For each type of fuel cell add-on module,
you will find background information pertaining to the models, a theoretical discussion of the models
used in ANSYS Fluent, and a description of using the models for your CFD simulations. The available
ANSYS Fluent add-on fuel cell modules are:
• Fuel Cell and Electrolysis Model - allows you to model polymer electrolyte membrane fuel cells (PEMFC),
solid oxide fuel cells (SOFC), and electrolysis with ANSYS Fluent. This model is sometimes referred to as
the Resolved Electrolyte model. For more information, see Fuel Cell and Electrolysis Model Theory (p. 1)
and Using the Fuel Cell and Electrolysis Model (p. 13).
• SOFC With Unresolved Electrolyte Model - allows you to model solid oxide fuel cells (SOFC). For more in-
formation, see
SOFC Fuel Cell With Unresolved Electrolyte Model Theory (p. 49) and Using the Solid Oxide
Fuel Cell With Unresolved Electrolyte Model (p. 59).
2.The Contents of the Fluent Manuals
The manuals listed below form the Fluent product documentation set. They include descriptions of the
procedures, commands, and theoretical details needed to use Fluent products.
•
Fluent Getting Started Guide contains general information about getting started with using
Fluent and provides details about starting, running, and exiting the program.
• Fluent Migration Manual contains information about transitioning from the previous release of Fluent,
including details about new features, solution changes, and text command list changes.
• Fluent User's Guide contains detailed information about running a simulation using the solution
mode of Fluent, including information about the user interface, reading and writing files, defining
boundary conditions, setting up physical models, calculating a solution, and analyzing your results.
• ANSYS Fluent Meshing User's Guide contains detailed information about creating 3D meshes
using the meshing mode of Fluent.
• Fluent in Workbench User's Guide contains information about getting started with and using Fluent
within the Workbench environment.
• Fluent Theory Guide contains reference information for how the physical models are implemented
in Fluent.
•
Fluent UDF Manual contains information about writing and using user-defined functions (UDFs).
v
Release 15.0 - © SAS IP, Inc. All rights reserved. - Contains proprietary and confidential information
of ANSYS, Inc. and its subsidiaries and affiliates.
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