International Journal of Minerals, Metallurgy and Materials
Volume 22, Number 5, May 2015, Page 516
DOI: 10.1007/s12613-015-1101-3
Corresponding author: Nai-qin Zhao E-mail: nqzhao@tju.edu.cn
© University of Science and Technology Beijing and Springer-Verlag Berlin Heidelberg 2015
Microstructural evolution in Al–Zn–Mg–Cu–Sc–Zr alloys during short-time
homogenization
Tao Liu
1)
, Chun-nian He
1,2)
, Gen Li
1)
, Xin Meng
1)
, Chun-sheng Shi
1)
, and Nai-qin Zhao
1,2)
1) Department of Materials Science and Engineering, Tianjin University; Tianjin Key Laboratory of Composite and Functional Materials, Tianjin 300072, China
2) Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China
(Received: 15 September 2014; revised: 27 November 2014; accepted: 1 December 2014)
Abstract: Microstructural evolution in a new kind of aluminum (Al) alloy with the chemical composition of Al–8.82Zn–2.08Mg–
0.80Cu–0.31Sc–0.3Zr was investigated. It is found that the secondary phase MgZn
2
is completely dissolved into the matrix during a short
homogenization treatment (470°C, 1 h), while the primary phase Al
3
(Sc,Zr) remains stable. This is due to Sc and Zr additions into the Al al-
loy, high Zn/Mg mass ratio, and low Cu content. The experimental findings fit well with the results calculated by the homogenization diffusion
kinetics equation. The alloy shows an excellent mechanical performance after the short homogenization process followed by hot-extrusion
and T6 treatment. Consequently, a good combination of low energy consumption and favorable mechanical properties is obtained.
Keywords: aluminum alloys; microstructural evolution; short-time; homogenization; grain refinement
1. Introduction
Al–Zn–Mg–Cu (7xxx series) alloys have been widely
used in the aeronautical and manufacturing industries be-
cause of their high strength, sufficient stress corrosion
cracking resistance (SCC), and satisfactory plasticity [1–2].
However, the disadvantages caused by the non-equilibrium
phases consisting of Zn, Mg, and Cu elements, which form
during casting, are also obvious; these disadvantages include
a severe cracking tendency, which leads to a great reduction
in strength and toughness after heat treatment and mechani-
cal deformation, along with poor SCC resistance. In order to
prevent from microsegregation and dissolve the secondary
phases, homogenization heat treatment is essential. Many
researchers have focused on the optimum homogenization
treatment parameters [3–8]; Li et al. [3] claimed that the op-
timum temperature and duration of homogenization for
Al–Zn–Mg–Cu–Sc–Zr alloys are 470°C and 24 h, respec-
tively. Deng et al. [7] designed a three-stage homogeniza-
tion heat treatment for Al–Zn–Mg–Cu alloys consisting of a
small amount of trace Zr. However, based on these refer-
ences, energy depletion and poor operation may be caused
by the long holding time (12–48 h) and the complex ho-
mogenization process (more than one step) in industrial
production.
Previous studies have shown that Sc and Zr are the most
efficient modification agents among all microalloying addi-
tions to Al [9–12]. By adding Sc and Zr to Al alloys, the
equiaxed grains and uniformly distributed second phase par-
ticles will form in the as-cast alloy rather than as long den-
drites [13–17]. Consequently, both the diffusion distance of
the alloying elements and the homogenization treatment pe-
riod can be shortened, which is beneficial for increasing the
efficiency and reducing the energy consumption.
In this work, the microstructural evolution of an
Al–Zn–Mg–Cu–Sc–Zr alloy during homogenization was
studied. It is found that after a short homogenization treat-
ment, the alloy reaches a homogeneous state. The observed
findings fit well with the results of the homogenization dif-
fusion kinetic equation.
2. Materials and methods
A semi-continuous ingot with the diameter of 60 mm