氩离子轰击模拟Zircaloy-4辐照损伤研究

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"Irradiation damage simulation of Zircaloy-4 using argon ions bombardment (2008年)" 是一篇2008年发表于《北京科技大学学报》第15卷第3期的文章,由Dequan Peng、Xinde Bai和Feng Pan合作完成。文章探讨了通过氩离子轰击模拟锆合金Zircaloy-4的辐射损伤,旨在理解这种材料在核反应堆中的行为。 文章的核心内容是利用加速器在190 kV的提取电压下,以液氮温度对Zircaloy-4进行氩离子注入,注入剂量范围从1 × 1016到1 × 1017 cm-2。这项实验模拟了实际核环境中材料可能遭遇的高能粒子辐射情况。实验结果显示,氩离子植入对Zircaloy-4的水腐蚀行为产生了显著影响。 作者们通过X射线光电子能谱(XPS)分析了样品表面层元素的价态变化,以了解氩离子植入后材料化学状态的变化。同时,借助透射电子显微镜(TEM)检查了氩离子植入后的微观结构,以揭示材料内部的结构损伤和相变。 根据XPS的结果,可以推断氩离子的植入改变了Zircaloy-4表面的氧化状态,可能形成新的化合物或改变原有氧化物的分布。而TEM的观察则揭示了氩离子导致的晶格缺陷、位错和可能的微观裂纹,这些结构变化可能影响材料的耐腐蚀性和机械性能。 此外,文章可能还讨论了这些变化对Zircaloy-4在核反应堆中长期服役的潜在影响,包括其在高温高压水环境下的耐蚀性和安全性。通过这样的模拟实验,研究者可以预测和评估Zircaloy-4在真实辐射条件下的性能退化,从而为核反应堆材料的设计和改进提供理论依据。 这篇文章是一篇工程技术领域的学术论文,通过实验手段深入研究了Zircaloy-4在模拟辐射条件下的行为,对于理解和改善核能领域关键材料的性能具有重要意义。
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润色下面英文:The controlled drug delivery systems, due to their precise control of drug release in spatiotemporal level triggered by specific stimulating factors and advantages such as higher utilization ratio of drug, less side-effects to normal tissues and so forth, provide a new strategy for the precise treatment of many serious diseases, especially tumors. The materials that constitute the controlled drug delivery systems are called “smart materials” and they can respond to the stimuli of some internal (pH, redox, enzymes, etc.) or external (temperature, electrical/magnetic, ultrasonic and optical, etc.) environments. Before and after the response to the specific stimulus, the composition or conformational of smart materials will be changed, damaging the original balance of the delivery systems and releasing the drug from the delivery systems. Amongst them, the photo-controlled drug delivery systems, which display drug release controlled by light, demonstrated extensive potential applications, and received wide attention from researchers. In recent years, photo-controlled drug delivery systems based on different photo-responsive groups have been designed and developed for precise photo-controlled release of drugs. Herein, in this review, we introduced four photo-responsive groups including photocleavage groups, photoisomerization groups, photo-induced rearrangement groups and photocrosslinking groups, and their different photo-responsive mechanisms. Firstly, the photocleavage groups represented by O-nitrobenzyl are able to absorb the energy of the photons, inducing the cleavage of some specific covalent bonds. Secondly, azobenzenes, as a kind of photoisomerization groups, are able to convert reversibly between the apolar trans form and the polar cis form upon different light irradiation. Thirdly, 2-diazo-1,2-naphthoquinone as the representative of the photo-induced rearrangement groups will absorb specific photon energy, carrying out Wolff rearrangement reaction. Finally, coumarin is a promising category photocrosslinking groups that can undergo [2+2] cycloaddition reactions under light irradiation. The research progress of photo-controlled drug delivery systems based on different photo-responsive mechanisms were mainly reviewed. Additionally, the existing problems and the future research perspectives of photo-controlled drug delivery systems were proposed.

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