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Principles of Quantum Mechanics(Dirac).pdf
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THE
PRINCIPLES
OF
QUANTUM MECHANICS
by
P. A. M. DIRAC
Typewritten by D. B. Ling
Department of Physics, Anhui University, Hefei
lingdb@ahu.edu.cn
21 November, 2006
PREFACE TO THE FOURTH EDITION
The main change from the third edition is that the chapter on quantum
electrodynamics has been rewritten. The quantum electrodynamics given
in the third edition describes the motion of individual charged particles
moving through the electromagnetic field, in close analogy with classical
electrodynamics. It is a form of theory in which the number of charged
particles is conserved and it cannot be generalized to allow of variation of
the number of charged particles.
In present-day high-energy physics the creation and annihilation of
charged particles is a frequent occurrence. A quantum electrodynamics
which demands conservation of the number of charged particles is there-
fore out of touch with physical reality. So I have replaced it by a quan-
tum electrodynamics which includes creation and annihilation of electro-
positron pairs. This involves abandoning any close analogy with classical
electron theory, but provides a closer description of nature. It seems that
the classical concept of an electron is no longer a useful model in physics,
except possibly for elementary theories that are restricted to low-energy
phenomena.
P. A. M. D.
st. john’s college, cambridge
11 May 1957
ii
FROM THE PREFACE TO THE FIRST EDITION
The methods of progress in theoretical physics have undergone a vast
change during the present century. The classical tradition has been to con-
sider the world to be association of observable objects (particles, fluids,
fields, etc.) moving about according to definite laws of force, so that one
could form a mental picture in space and time of the whole scheme. This
led to a physics whose aim was to make assumptions about the mecha-
nism and forces connecting these observable objects, to account for their
behavior in the simplest possible way. It has become increasingly evident
in recent times, however, that nature works on a different plan. Her fun-
damental laws do not govern the world as it appears in our mental picture
in any very direct way, but instead they control a substratum of which we
cannot form a mental picture without introducing irrelevancies. The for-
mulation of these laws requires the use of the mathematics of transforma-
tions. The important things in the world appear as the invariants (or more
generally the nearly invariants, or quantities with simple transformation
properties) of these transformations. The things we are immediately aware
of are the relations of these nearly invariant to be a certain frame of ref-
erence, usually one chosen so as to introduce special simplifying features
which are unimportant from the point of view of general theory.
The growth of the use of transformation theory, as applied first to rel-
ativity and later to the quantum theory, is the essence of the new method
in theoretical physics. Further progress lies in the direction of making
our equations invariant under wider and still wider transformations. This
state of affairs is very satisfactory from a philosophical point of view, as
implying an increasing recognition of the part played by the observer in
himself introducing the regularities that appear in his observations, and a
lack of arbitrariness in the ways of nature, but in makes things less easy
for the learner of physics. The new theories, if one looks apart from their
mathematical setting, are built up from physical concepts which cannot
be explained in terms of things previously known to the student, which
cannot even be explained adequately in words at all. Like the fundamen-
tal concepts (e.g. proximity, identity) which every one must learn on his
arrival into the world, the newer concepts of physics can be mastered only
by long familiarity with their properties and uses.
From the mathematical side the approach to the new theories presents
no difficulties, as the mathematics required(at any rate that which is re-
quired for the development of physics up to the present) is not essentially
different from what has been current for a considerable time. Mathemat-
ics is the tool specially suited for dealing with abstract concepts of any
kind and there is no limit to its power in this field. For this reason a book
on the new physics, if not purely descriptive of experimental work, must
be essentially mathematical. All the same the mathematics is only a tool
and one should learn to hold the physical ideas in one’s mind without
reference to the mathematical form. In this book I have tried to keep the
iii
iv FROM THE PREFACE TO THE FIRST EDITION
physics to the forefront, by beginning with an entirely physical chapter
and in the later work examining the physical meaning underlying the for-
malism wherever possible. The amount of theoretical ground one has to
cover before being able to solve problems of real practical value is rather
large, but this circumstance is an inevitable consequence of the funda-
mental part played by transformation theory and is likely to become more
pronounced in the theoretical physics of the future.
With regard to the mathematical form in which the theory can be pre-
sented, an author must decide at the outset between two methods. There
is the symbolic method, which deal directly in an abstract way with the
quantities of fundamental importance (the invariants, etc., of the transfor-
mations) and there is the method of coordinates or representations, which
deals with sets of numbers corresponding to these quantities. The second
of these has usually been used for the presentation of quantum mechan-
ics (in fact it has been used practically exclusively with the exception of
Weyl’s book Gruppentheotie und Quantenmechanik). It is known under one
or other of the two names ‘Wave Mechanics’ and ‘Matrix Mechanics’ ac-
cording to which physical things receive emphasis in the treatment, the
states of a system or its dynamical variables. It has the advantage that the
kind of mathematics required is more familiar to the average student, and
also it is the historical method.
The symbolic method, however, seems to go more deeply into the na-
ture of things. It enables one to express the physical laws in a neat and
concise way, and will probably be increasingly used in the future as it
becomes better understood and its own special mathematics gets devel-
oped. For this reason I have chosen the symbolic method, introducing the
representatives later merely as an aid to practical calculation. This has
necessitated a complete break from the historical line of development, but
this break is an advantage through enabling the approach to the new ideas
to be made as direct as possible.
P. A. M. D.
st. john’s college, cambridge
29 May 1930
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